![]() A single bond, double bond, triple bond, a lone pair, or a single electron count as a single electron group. Here we will discuss both electron pair geometries (also called electron group or electron domain geometries) and molecular geometries (also called molecular shapes).Ī group of electrons is any number of electrons that occupies a localized region around an atom. We use the Valence Shell Electron Pair Repulsion (VSEPR) model to predict the shapes of molecules. The regions of electrons density, bonds and nonbonding electrons, will repel one another and therefore orient as far away from each other as they possibly can to minimize these repulsions. ![]() If four balloons are tied together, each balloon will orient to a corner of a tetrahedron with angles of 109.5 o.Įlectrons in molecules will act similarly to the balloons. If we add a third balloon, we see the balloons point to the corners of an equilateral triangle with angles of 120 o apart. In fact, the balloons are 180 o apart and have a linear orientation. The balloons will point away from one another as shown in the figure below. Imagine two equal sized balloons that are tied together. ![]() Molecules and ions are three dimensional and we have only learned how to draw two dimensional shapes. Lewis structures do not tell us anything about molecular shape. ![]() Lewis structures were used previously to determine how the atoms are connected in a molecule and show where the lone pairs of electrons are located. ![]()
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![]() ![]() Neither the present nor the future situation of the questioner’s concern is perfectly auspicious, though both are still largely positive. That’s why ancient Confucian scholars insisted that the book be read together with their commentaries, which they named the Ten Wings ( 十翼)-without which readers of the I Ching could not “fly” high.Ī visualization of the Ten Wings for I Ching (adapted from new.qq.com)Ībstruse as they are, the central messages in the two judgments are clear enough. This is not a translation issue, as the original Chinese texts are equally (if not more) abstruse. How is this to be carried out? One may use two small bowls for the sacrifice.Īs we can see, the judgments are quite abstruse and filled with metaphors. Sun: Decrease combined with sincerity brings about supreme good fortune without blame. But if the little fox, after nearly completing the crossing, gets his tail in the water, there is nothing that would further. Reading through the respective chapters in the I Ching (i.e., Chapter 64 and Chapter 41), we find the following judgments: 2 ![]() Screenshots from the contents of the I Ching (source: Amazon) 1 The status quo of the questioner’s concern is in “before completion” and its future development is in “decrease.” For example, the two hexagrams in the previous post are respectively called wei chi ‘before completion’ ( 未濟 ䷿) and sun ‘decrease’ ( 損 ䷨). This is also the easiest level for beginners, because one simply needs to look up a hexagram in the book and read it. Interpretation of I Ching divination results traditionally starts from the hexagram level. ![]() Impatient readers can jump to the summary. Two posts are dedicated to this topic because result interpretation is the most complex part of I Ching divination. In this and the next post I’ll write about how those components are interpreted. In the previous post I introduced the structural components of I Ching divination, including lines (or monograms), trigrams, and hexagrams. ![]() ![]() ![]() I have also rewritten the algorithm for Drop Shadows to make them look better and be easier to use.Īlso, I updated my Render > Chart plugin which had stopped working because of a change in Paint.NET. Many people found the combined shadow plugin too complicated to use. I have also split Object Shadow Pro into two different plugins: Object Shadow (which handles all 2D shadows, including Drop Shadow and Modern Shadow) and Object Shadow 3D which handles only the 3D shadows: "Transparent Flames" renders the same flames but on a transparent canvas so you can add them to your favorite photo more easily. While doing so, I added a new features to many of the plugins, improved the output of some, and I optimized the code to run faster in almost all cases.įor example, here is a comparison of the previous version of Render > Flames (left) and the new version (right): So, in this pack I have gone through all of my plugins and rewritten them from scratch. My laptop crashed and I lost all of the code for my plugins. for more information: C:\> BoltBaitPackInstall52.exe /? This will make sure your system has all the latest updates!įor high volume network managers: Plugin Manager has a silent install function. Just click "Apply to all files" and then click the "Overwrite" button. If you've had my plugins installed on your system before, you will see the following warning: When you click the Install button, checked items will be installed and unchecked items will be uninstalled from your system. However, if nothing is installed, it automatically checks ALL the boxes figuring the user would like to install everything.Ĭarefully review each line and make sure the items you wish to install are checked. When the installer first runs, it updates the check boxes to what's currently installed (checked for installed, unchecked for not installed). Once you click the download button above and open the zip file, run the included BoltBaitPackInstall52.exe file. When you see the main screen (shown below), select the "I'm running the store version of Paint.NET" checkbox. Windows Store version of : You're in the right place! Click the download button above You need to look at the Paint.NET version number in the title bar.Ĥ.3.10+ You're in the right place! Click the download button above (surrounded by blue arrows) Which of my plugin packs is right for you? So anything you can spare would be much appreciated. ![]() I'm going through a really tough financial time right now, Note: This is an older version of my plugin pack for v4.3.12. To install, download this file to your Desktop, unzip it, and run the install program. When you see in this post, you can click it for more information (including source code in some cases). ![]() Then, later you can run the installer and uncheck an item to uninstall it. This allows you to pick and choose to install only the effects you want. It includes 46 plugins in 38 files, 2 palette files, and 50+ shapes. Save/Load settings option is also on my wishlist (wish I knew how to do it :wink: ).Here is what I consider my "Essential", award winning, plugin pack for Paint.NET v4.3.10 and beyond. I have thought about placing all the hue nubs into a single continuous hue-gradient bar. I may want to improve the UI soon, so far all your requests are welcome. This pic asks for some saturation, but regular saturation adjustment is likely to make sky over-saturated. You can adjust saturation, brightness, contrast and hue for each color (hue) range separately or all together.Īmount of adjustment between the ranges is changed gradually, so there is no sharp cut-off, for example between red and yellow.ĭue to high precision calculations in the code, this plugin renders saturation and hue better than PdN's original Hue/Saturation effect. This plugin is designed for fine color adjustments. ![]() ![]() ![]() We encountered three patients with initial findings of left supraclavicular lymph node metastasis before detection of the primary infradiaphragmatic tumor during follow-up after surgery for tongue cancer. The incidence of metastasis has been reported to be 3.6% for intrahepatic cholangiocarcinoma, 1.4% for bladder carcinoma, and approximately 0.3% for prostate carcinoma. Metastasis of infradiaphragmatic tumors to the left supraclavicular lymph node is also reported to be rare. In contrast, second primary cancer at other sites, such as the intrahepatic bile duct, bladder, and prostate, is rare in patients with tongue carcinoma. In patients with tongue carcinoma, the second primary cancer most frequently occurs in the oropharynx, followed by the esophagus and larynx. reported that the risk of a second primary oral cancer was higher (standardized incidence ratio 16.25, 95% confidence interval 13.04–20.02) than that of nonoral second primary cancer (standardized incidence ratio 1.37, 95% confidence interval 1.29–1.45) in Korean patients with cancer in the oral cavity. found a second primary cancer in 10% of patients with oral squamous cell carcinoma in their cohort, while Min et al. Patients with oral squamous cell carcinoma and those with other types of head and neck cancer are at higher risk of second primary cancer than patients with cancers at most other sites. The accumulation of cases and the search for optimal therapeutic strategies remain important. ![]() However, when metastasis is detected in the left supraclavicular node in patients with head and neck carcinoma, locating the primary cancer remains a difficult and time-consuming challenge. Supraclavicular lymph node metastasis has been reported to be more common in patients with lung and breast tumors (18.7% and 18.6%, respectively). Since Virchow's time, the survival rates of cancer patients have improved because of dramatic research advances in the epidemiology of cancer and the development of screening technologies and treatment methods. Pathological diagnosis on the basis of immunohistochemistry and specific diagnosis methods such as radiological and serological assessments are important for providing rapid diagnosis and appropriate treatment. This patient underwent bilateral orchiectomy and adjuvant hormonal therapy and survived for 47 months after diagnosis of left supraclavicular node metastasis. Prostate-specific antigen levels and magnetic resonance imaging findings aided the diagnostic process. In the prostate carcinoma case, 18F‐fluorodeoxyglucose uptake was weak. He survived for 2 months after diagnosis of left supraclavicular lymph node metastasis. GATA3 staining aided in the diagnosis of urothelial bladder cancer with left supraclavicular node metastasis. Hematoxylin–eosin staining of the bladder lesion did not identify a clear glandular or squamous component, and we could not make a definitive diagnosis of whether the lesion was poorly differentiated squamous cell carcinoma, adenocarcinoma, or high-grade urothelial carcinoma. In the bladder carcinoma case, pathological analysis of fine-needle aspiration biopsy specimen of the metastatic cervical lymph node showed atypical cells with slight squamous differentiation. Palliative care only was given, with survival for 11 months after diagnosis of lymph node metastasis. ![]() In the cholangiocarcinoma case, carbohydrate antigen 19-9 and alpha-fetoprotein levels helped to diagnose cholangiocarcinoma. In these cases, adenocarcinoma was diagnosed based on left supraclavicular node biopsies, and a second primary tumor was found, in a 78-year-old Japanese woman with a diagnosis of cholangiocarcinoma, a 64-year-old Japanese man with a diagnosis of bladder carcinoma, and a 61-year-old Japanese man with a diagnosis of prostate carcinoma. We report three cases of malignant infradiaphragmatic tumor diagnosed following an initial finding of left supraclavicular node metastasis after surgery for tongue squamous cell carcinoma (follow-up period, range 18–62 months). When metastasis is detected in the left supraclavicular node in patients with head and neck carcinoma, locating the primary cancer remains a difficult and time-consuming challenge despite the dramatic development of screening technologies and treatment methods. Metastasis of infradiaphragmatic tumors to the left supraclavicular lymph node is reported to be rare. ![]() ![]() ![]() Items for one time wear or indoor use like shoe covers, boots tops, costume shoes, etccan not be returned.Undergarments, socks and stocking can not be returned.Worn, used, stained, animal hair attached or altered items can not be returned.If you return part of the costumes, the payment can not be refunded.!!!Special Sale items/Clearance products can not be returned for refund, we can offer exchange for them but only the sizes in stock can be exchanged. Please return the costumes back with a shipping number.įollowing are conditions on which return is not accepted: Thus, be careful while checking all details on the merchandise please. ![]() The original package, garment tag and tracking number are must-have items for you to receive the refund.
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![]() ![]() I can tip in BTC/LTC and would immensely appreciate it. If anyone has the programming know-how to accomplish this, I would be very interested in speaking to you. jpg image for example, "Humidity 43.1%" and then save the image with the overlay. jpg image file to find the closest timestamp value in the specified CSVįor image name "20140227-134726.jpg" -Taken at 01:47:26 PMģ. How it works How to convert JPG to CSV Step 1 Click inside the file drop area to upload JPG file or drag & drop JPG file. jpg image files from a specified folderĢ. Choose one or multiple files and start the csv conversion. With Convertall, converting csv files to jpg is extremely easy. I assume I would need a script that would:ġ. The best solution to convert csv files to jpg. Python or Perl is what I would assume someone would turn to for help at this point. I agree that a database tool would be much better suited for that purpose. I understand that ImageMagick is limited for such a "matching" operation. It won't search through CSV files looking for the closest date/time match. This is a simple database style data-processing operation. Can someone help me write a command for ImageMagick (windows), which can find and convert all the svgs to jpg/png with their original names and keep them in the same directories Here is the example structure: C:SVGBusinessMan. How it works How to convert CSV to JPG Step 1 Click inside the file drop area to upload CSV file or drag & drop CSV file. For each one, you want to find the nearest entry in each of two CSV files. JPG or JPEG is a digital image format created by the Joint Photographic Experts Group in 1992. Snibgo wrote:You have a list of filenames representing date/times. I know it sounds easy, but for a non-programmer, it isn't. csv files which contain data I wish to overlay onto all the images I have taken.Īnybody have any clue how I could import the data from the CSV files, match the image timestamp to the closest timestamp of the CSV file, then overlay the corresponding temperature and humidity values onto an image? I have image files in a folder with each file using a naming convention which utilizes the date and time the image was taken: I'm new to programming and am attempting to write my first script with imagemagick but am somewhat lost. Use the magick program to convert between image formats as well as resize an image, blur, crop, despeckle, dither, draw on, flip, join, re-sample, and much more. Convert your file from Comma Separated Values File to Joint Photographic Experts Group JFIF format with this CSV to JPG converter. First post and I hope someone can provide useful information for how I can get started. ![]() ![]() ![]() This allows you to save your mobile data for other important tasks and activities. SHAREit operates offline, ensuring that all your file sharing is data-free. But with SHAREit, you can rest easy knowing you won't incur any data costs. Save your precious dataĭata charges can quickly add up, especially when transferring large files. ![]() This is especially helpful when you're on the go and don't have access to a reliable internet connection. This unique feature allows you to transfer files directly between devices, bypassing the need for Wi-Fi or mobile data. With SHAREit.No internet connection? No problem! SHAREit thrives even without it. ❤️ Download SHAREit now! It's the perfect app to share and transfer files! If you like it, SHARE it with your friends! ❤️ TRANSFER GAME APPS: A new PUBG One Click Transmission feature - within seconds transfer large game apps, without needing to download the game cache file.ĭOWNLOADER: Save videos and photos from WhatsApp, Facebook and Instagram for free.įILE MANAGER: Manage the biggest files, move files or delete them. Samsung, Transsion, Xiaomi, OPPO, vivo, Huawei, OnePlus, iPhone and other smartphones all support this function. You can easily transfer contacts, apps, videos, photos, music, recordings, documents from old phone to new phone without internet connection. Phone Clone (Smart Switch) is a very handy data migration function when you change phones. It's so much more than just a music player: it's a powerful and easy-to-use audio player. SHAREit Music Player is the best way to listen to your favorite songs. Watch unlimited high-definition online videos find high-quality and fun new video content every time you open the app. Easily download videos and photos directly from the Internet onto your device. Supports downloading videos and photos from 100+ websites. Transfer: Apps, Games, Photos, Movies, Videos, Music, GIFs and Wallpapers with just one tap! You don't have to worry about the size or type of data anymore because SHAREit helps you send large files without limitation across all your devices. □ POWERFUL CROSS-PLATFORM TRANSFERRING, SUPPORTS ALL TYPES OF FILESĮxperience the best data-free file transferring and sharing app that offers cross-platform transferring, supports all types of files and makes your life easier. With SHAREit, you can quickly and securely send and share any file, anywhere in the world. We know that privacy and data security are important, so we make sure they're protected in the best way while you enjoy your files transfer, for free. Share and receive files without any data consumption, transfer files without any quality loss. With 200 times faster than Bluetooth, the highest speed goes up to 42MB/s. □ THE FASTEST FILE SHARING AND APP SHARING IN THE WORLD, OFFLINE & ONLINE □ Why you must use SHAREit, the #1 file share & data transfer app? It's super easy to use! And the best part? Its free! New function: when you change your phone, you can easily transfer contacts, apps, videos, photos, music, recordings, documents from the old phone to the new one without a network connection through SHAREit's phone clone function. Transferring files from Mobile to PC and vice versa is now faster and easier. With SHAREit you can also download videos and photos directly from the Internet onto your device with downloader, manage files on your phone with file manager. Trusted by 2 billion+ users worldwide, SHAREit is the secure way to share your files, online & offline. SHAREit is a super-fast, data-free and safe app to transfer big files. Share files, apps, games, videos, photos, music, recordings, documents and more with the SHAREit file transfer app. ![]() ![]() ![]() With an emphasis on learning at its core, the company has developed a specialized version of its software for educational settings. Screencastify is a web app that records your computer screen as you use the Chrome web browser. Offers a premium version with extensive editing options is offered for sophisticated and customized films.Users may be engaged by drawing on and zooming in on videos.Users are provided a direct uploading option to YouTube for their recorded videos.A free service that records your screen and webcam in one convenient package.Overlays, text notes, comments, and the like may enhance recorded videos. The resolution of any video you plan on recording and sharing online must be at least 800 by 600 pixels to be considered “standard.” Screencast-o-Matic lets you easily capture high-quality video that meets the recommended resolution specifications. You can easily capture what’s happening on your screen and share the recording instantly on your preferred social networking platform. Screen-o-Matic ranks high among the top online screen recorders available for recording your screen without paying anything. Want to know how to record screen online for free, check out here: Screencast-o-Matic Let’s get going! 10 Best Free Online Screen Recorders In this article, you’ll get the finest free online screen records along with their features. And if you’re unaware of the best Online Free Screen Recorder, we’ve got you covered. But the introduction of online screen recorders such as Gemoo’s Online Screen Recorder has solved this problem for people. ![]() ![]() However, you had to pay for software to record the screen in high-quality, which is not feasible if you’re working on a budget. ![]() ![]() Whether you’re looking to improve your workflow or add some personal flair to documents, there are plenty of possibilities with Excel. Let’s also talk about customizing Excel to fit your needs. In the “Border Style” drop-down menu, pick one of the options with rounded edges.īy following these steps, you can transform ordinary cells into something much nicer. ![]() Click “Format Cells” and then select “Border”.Go to the “Home” tab and click “Format”.Changing the Shape of an Existing Cellĭo you want to make your Excel spreadsheets more visually appealing? Here’s a guide to changing the shape of existing cells! You can also adjust the shape of an existing cell if you need more control over your visuals. Change line thicknesses or add dual colors for an extra effect. Pro tip: You can customize your rounding further by selecting more formatting options under “Border Edge Styles”. For example, if you have region-wise sales reports or quarterly project updates, you can differentiate these groups with rounded corners. In the “Format Cells” dialogue box, click the “Border” tab and pick the desired rounded corner style.Īdding rounded corners to cells can be useful if you want to make your spreadsheet look more professional or separate related data points.Open the “Format Cells” window – either right-click and select “Format Cells” or go to the “Home” tab and pick “Format” from the dropdown menu.Choose the cell or range you want to modify.In Excel, you can make a cell with rounded corners easily. Image credits: by Harry Duncun Creating a New Cell with Rounded Corners With these tips and tricks, you can add flair to your spreadsheets and wow colleagues and clients. We’ll also explain how to adjust the rounded corners to your needs. You can create and format a new cell or alter an existing cell. How to Add Rounded Corners in ExcelĮver pondered how to make rounded edges on cells in Excel? Good news! This article shows you different methods. ![]() Surprisingly, many people think Apple invented this feature, but it was actually first seen in web design in the late 90s. Adding rounded corners is easy and doesn’t require HTML coding expertise. Lastly, it allows you to customize the size and shape of each cell. Secondly, it helps users find data points quickly and makes fewer errors. It is also much easier to read and navigate. Firstly, they improve the look of your spreadsheet and make it attractive. Rounded corners on cells in Excel have several advantages.
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